Fairlamb Research Group

Catalysis, Synthetic and Mechanistic Chemistry

Complex NMR spectroscopy

From time to time more complex NMR spectra are obtained for some of the metal complexes that we prepare.  An example is the binuclear palladium(0) complex containing the FLEXIphosO ligand:

Lead references:

NMR - Eur. J. Inorg. Chem. 2007, 3173-3178.

Catalysis - Adv. Synth. Cat. 2006348, 2515-2530.



Experimental (upper) and simulated (lower) 31P NMR spectra for Pd02(FLEXIphosO)3 (mixture of isomers).


Table of NMR data. Simulated 31P NMR spectroscopic data for Pd02(FLEXIphosO)3(values in Hertz; chemical shift in ppm).

P environment δ JA JB JC JD JE
A 109.3          
B 109.5 0        
C 108.4 0 116.0      
D 113.6 0 123.7 126.8    
E 112.9 107.8 0 0 0  
F 115.0 108.7 0 0 0 100.4

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